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Journal articles
Controllable conversion of cellulose nanocrystals to cellulose microspheres: Insight on the effect of parameters during spray drying, TAPPI Journal February 2025

ABSTRACT: Cellulose microspheres, which have mainly been produced via the sol-gel method up until now, exhibit a promising potential for broad applications due to their regular microstructure and renewability. However, some issues with production of cellulose microspheres, such as the recycling of involved organic solvents and the removal of the residual solvents, should be solved. In this study, a cellulose nanocrystals (CNCs) suspension was used to produce cellulose microspheres via spray drying in order to avoid the use of organic solvents. The effects of CNCs particle size, CNCs concentration, and inlet temperature of spray drying on microstructure and particle size of cellulose microspheres were investigated. The results indicated that the optimal average particle size and concentration of CNCs used for obtaining cellulose microspheres were 106 nm and 0.1 wt%, respectively. Under the optimal conditions, cellulose microspheres with a regular spherical morphology and an average particle size of ca. 3 ìm were obtained. The sulfuric acid hydrolysis and spray drying process barely affected the crystalline structure of cellulose. However, the introduced sulfhydryl groups, which were confirmed by Fourier transform infrared spectroscopy results, degraded the thermostability of cellulose. Generally speaking, converting CNCs to cellulose microspheres via spray drying is beneficial for promoting the controllable and continuous production of cellulose microspheres.

Polymeric Nanocomposites Enabled by Controlled Architecture Materials, 2005 PLACE Conference

Polymeric Nanocomposites Enabled by Controlled Architecture Materials, 2005 PLACE Conference

Magazine articles
Open Access
Nanoparticle prospects & perspectives, TAPPI JOURNAL, May 2000, Vol. 83(5)

Nanoparticle prospects & perspectives, TAPPI JOURNAL, May 2000, Vol. 83(5)

Journal articles
Open Access
Novel all-cellulose composite displaying aligned cellulose nanofibers reinforced with cellulose nanocrystals, TAPPI JOURNAL April 2011

Novel all-cellulose composite displaying aligned cellulose nanofibers reinforced with cellulose nanocrystals, TAPPI JOURNAL April 2011

Journal articles
International cooperation needed for nano standardization, Paper360° July/August 2011

International cooperation needed for nano standardization, Paper360º July/August 2011

Conference papers
Paper Composites for Improved Wet Strength and Water Barrier Properties, 2011 TAPPI International Conference on Nanotechnology for Renewable Materials

Paper Composites for Improved Wet Strength and Water Barrier Properties, 2011 TAPPI International Conference on Nanotechnology for Renewable Materials

Conference papers
THIN FILM DEPOSITION TECHNIQUES â?¢ STEPS TOWARDS MORE SUSTAINABLE PACKAGES, 2010 TAPPI International Conference on Nanotechnology for the Forest Product Industry

THIN FILM DEPOSITION TECHNIQUES • STEPS TOWARDS MORE SUSTAINABLE PACKAGES, 2010 TAPPI International Conference on Nanotechnology for the Forest Product Industry

Books
Polymer Nanocomposites Handbook

Polymer Nanocomposites Handbook

Journal articles
Nanotechnology is Ready to Transform Our Industry", Paper360º September/October 2013

Nanotechnology is Ready to Transform Our Industry, Paper360º September/October 2013

Journal articles
Open Access
Peculiarities of cellulose nanoparticles, TAPPI JOURNAL May 2014

Peculiarities of cellulose nanoparticles, TAPPI JOURNAL May 2014